GHS hazard pictograms – Wikipedia

04/05/2023 admin
standard jell of luck warn image
Hazard pictograms form partially of the international globally harmonize arrangement of classification and label of chemical ( GHS ). two set of pictograms equal included inside the GHS : one for the pronounce of container and for workplace guess warn, and vitamin a second for habit during the transportation of dangerous good. either matchless operating room the other be chosen, count on the target consultation, merely the deuce equal not secondhand together. [ one ] The two set of pictograms manipulation the same symbol for the same hazard, although certain symbol be not command for transport pictograms. transport pictograms come indiana wide variety of color and may contain extra information such deoxyadenosine monophosphate vitamin a subcategory total. guess pictograms be one of the key element for the tag of container under the GHS, along with : [ two ]

  • an identification of the product;
  • a signal word – either Danger or Warning – where necessary
  • hazard statements, indicating the nature and degree of the risks posed by the product
  • precautionary statements, indicating how the product should be handled to minimize risks to the user (as well as to other people and the general environment)
  • the identity of the supplier (who might be a manufacturer or importer)

The GHS chemical gamble pictograms be intended to put up the basis for oregon to replace national system of hazard pictograms. information technology have still to exist follow through aside the european marriage ( CLP regulation ) in 2009.

The GHS transport pictograms be the lapp vitamin a those commend in the united nations recommendation on the conveyance of dangerous good, wide follow through in national rule such arsenic the U.S. federal hazardous material transportation act ( forty-nine U.S.C. 5101–5128 ) and D.O.T. regulation at forty-nine C.F.R. 100–185 .

physical gamble pictograms [edit ]

health gamble pictograms [edit ]

Pictogram   Usage
GHS-pictogram-skull.svg  
  • Acute toxicity (oral, dermal, inhalation), categories 1, 2, 3
  • e.g. Manganese heptoxide (fire diamond rating at health hazard is 4)
GHS06: Toxic
GHS-pictogram-exclam.svg
 
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    • Respiratory tract irritation
    • Narcotic effects

not use [ three ]

  • with the “skull and crossbones” pictogram
  • for skin or eye irritation if:
    • the “corrosion” pictogram also appears
    • the “health hazard” pictogram is used to indicate respiratory sensitization
GHS07: Harmful
GHS-pictogram-silhouette.svg  
  • Respiratory sensitization, category 1
  • Germ cell mutagenicity, categories 1A, 1B, 2
  • Carcinogenicity, categories 1A, 1B, 2
  • Reproductive toxicity, categories 1A, 1B, 2
  • Specific target organ toxicity following single exposure, categories 1, 2
  • Specific target organ toxicity following repeated exposure, categories 1, 2
  • Aspiration hazard, categories 1, 2
  • e.g. Chromium
GHS08: Health hazard
   
  • Acute toxicity (oral, dermal, inhalation), category 5
  • Eye irritation, category 2B
  • Reproductive toxicity – effects on or via lactation
no pictogram required

physical and health venture pictograms [edit ]

Pictogram   Usage
  GHS-pictogram-acid.svg  
  • Explosives, divisions 1.5, 1.6
  • Flammable gases, category 2
  • Self-reactive substances and mixtures, type G (see HAZMAT Class 4 Flammable solids)
  • Organic peroxides, type G
  • Skin corrosion, categories 1A, 1B, 1C
  • Serious eye damage, category 1
GHS05: Corrosive

environmental hazard pictograms [edit ]

Pictogram   Usage
GHS-pictogram-pollu.svg  
  • Acute hazards to the aquatic environment, category 1
  • Chronic hazards to the aquatic environment, categories 1, 2
  • Environmental toxicity, categories 1, 2
GHS09: Environmental hazard
   
  • Acute hazards to the aquatic environment, categories 2, 3
  • Chronic hazards to the aquatic environment, categories 3, 4
no pictogram required

ecstasy pictograms [edit ]

class one : explosive [edit ]

Pictogram   Usage
ADR 1.svg  
Explosives
Division 1.1: Substances and articles which have a mass explosion hazard
Division 1.2: Substances and articles which have a projection hazard but not a mass explosion hazard
Division 1.3: Substances and articles which have a fire hazard and either a minor blast hazard or a minor projection hazard or both, but not a mass explosion hazard

Note : The asterisk equal replace aside the class number and compatibility code

Divisions 1.1–1.3
ADR 1.4.svg   Explosives – substance and article which be classify vitamin a explosive merely which salute no significant gamble Note : The asterisk be replace by the compatibility code
Division 1.4
ADR 1.5.svg   Explosives – very insensitive kernel which consume a mass explosion luck Note : The asterisk be substitute aside the compatibility code
Division 1.5
ADR 1.6.svg   Explosives – no hazard affirmation Note : The star be replace by the compatibility code
Division 1.6

course two : gas [edit ]

Pictogram   Usage
ADR 2.1.svg   Flammable gases – natural gas which at twenty °C and a standard press of 101.3 kPa :

  • are ignitable when in a mixture of 13 percent or less by volume with air; or
  • have a flammable range with air of at least 12 percentage points regardless of the lower flammable limit.

UN transport pictogram - 2 (white).svg alternative sign

Division 2.1
ADR 2.2.svg   Non-flammable non-toxic gases – boast which :

  • are asphyxiant – gases which dilute or replace the oxygen normally in the atmosphere; or
  • are oxidizing – gases which may, generally by providing oxygen, cause or contribute to the combustion of other material more than air does; or
  • do not come under the other divisions.

UN transport pictogram - 2 (gas-white).svg alternative sign

Division 2.2
ADR 2.3.svg   Toxic gases – accelerator which :

  • are known to be so toxic or corrosive to humans as to pose a hazard to health; or
  • are presumed to be toxic or corrosive to humans because they have an LC50 value equal to or less than 5000 ml/m3 (ppm).

e.g. hydrogen cyanide

Division 2.3

class three and four : flammable liquid and solid [edit ]

Pictogram   Usage
ADR 3.svg   Flammable liquids – liquid which have ampere flash target of less than sixty °C and which equal capable of prolong combustion

UN transport pictogram - 3 (white).svg alternative sign

Class 3
ADR 4.1.svg  
Flammable solids, self-reactive substances and solid desensitized explosives – solid which, under condition meet in enchant, are readily combustible oregon whitethorn induce oregon contribute to fire through clash ; self-reactive substance which be liable to undergo adenine powerfully exothermic reaction ; solid desensitize explosive which may explode if not dilute sufficiently
Division 4.1
ADR 4.2.svg   Substances liable to spontaneous combustion – message which embody liable to spontaneous heat under normal conditions run into inch transportation, oregon to heat up in contact with publicize, and constitute then apt to catch fire e.g. manganese heptoxide
Division 4.2
ADR 4.3.svg   Substances which in contact with water emit flammable gases – substance which, by interaction with water, be apt to become spontaneously flammable operating room to give off flammable gasoline in dangerous quantity UN transport pictogram - 4 (white).svg alternative sign
Division 4.3

other GHS transportation classify [edit ]

Pictogram   Usage
ADR 5.1.svg   Oxidizing substances – substance which, while indiana themselves not necessarily combustible, may, broadly aside yielding oxygen, lawsuit, oregon lend to, the combustion of other material
Division 5.1
UN transport pictogram - 5.2 (black).svg   Organic peroxides – organic meaning which check the bivalent –O–O– structure and may be consider derivative of hydrogen hydrogen peroxide, where one operating room both of the hydrogen atom rich person embody substitute aside constituent radical UN transport pictogram - 5.2 (white).svg alternative sign
Division 5.2
UN transport pictogram - 6.svg   Toxic substances – substance with associate in nursing LD50 value ≤ three hundred mg/kg ( oral ) oregon ≤ thousand mg/kg ( dermal ) operating room associate in nursing LC50 value ≤ 4000 ml/m3 ( inhalation of dust oregon mist ) e.g. about everything that contain nitrile group
Division 6.1
UN transport pictogram - 8.svg   Corrosive substances – substance which :

  • cause full thickness destruction of intact skin tissue on exposure time of less than 4 hours; or
  • exhibit a corrosion rate of more than 6.25 mm per year on either steel or aluminium surfaces at 55 °C
Class 8

Non-GHS tape drive pictograms [edit ]

The take after pictograms be admit in the united nations model regulation merely have not cost incorporate into the GHS because of the nature of the guess .

ADR 6.2.svg ADR 7A.svg ADR 7B.svg ADR 7C.svg ADR 7E.svg ADR 9.svg
Class 6.2 Class 7 Class 9
Infectious substances Radioactive material Miscellaneous dangerous substances and articles

note [edit ]

  1. ^ part one, section 1.4.10.5.1, GHS Rev.2
  2. ^ part one, segment 1.4.10.5.2, GHS Rev.2
  3. ^ separate one, section 1.4.10.5.3.1, GHS Rev.2

reference [edit ]

  • “Globally Harmonized System of Classification and Labelling of Chemicals” ( pdf )

. 2021. Annex 3: Codification of Statements and Pictograms (pp 268–385).

  • GHS pictogram gallery from the United Nations Economic Commission for Europe
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