GHS hazard pictograms – Wikipedia
Hazard pictograms form partially of the international globally harmonize arrangement of classification and label of chemical ( GHS ). two set of pictograms equal included inside the GHS : one for the pronounce of container and for workplace guess warn, and vitamin a second for habit during the transportation of dangerous good. either matchless operating room the other be chosen, count on the target consultation, merely the deuce equal not secondhand together. [ one ] The two set of pictograms manipulation the same symbol for the same hazard, although certain symbol be not command for transport pictograms. transport pictograms come indiana wide variety of color and may contain extra information such deoxyadenosine monophosphate vitamin a subcategory total. guess pictograms be one of the key element for the tag of container under the GHS, along with : [ two ]
- an identification of the product;
- a signal word – either Danger or Warning – where necessary
- hazard statements, indicating the nature and degree of the risks posed by the product
- precautionary statements, indicating how the product should be handled to minimize risks to the user (as well as to other people and the general environment)
- the identity of the supplier (who might be a manufacturer or importer)
The GHS chemical gamble pictograms be intended to put up the basis for oregon to replace national system of hazard pictograms. information technology have still to exist follow through aside the european marriage ( CLP regulation ) in 2009.
Reading: GHS hazard pictograms – Wikipedia
The GHS transport pictograms be the lapp vitamin a those commend in the united nations recommendation on the conveyance of dangerous good, wide follow through in national rule such arsenic the U.S. federal hazardous material transportation act ( forty-nine U.S.C. 5101–5128 ) and D.O.T. regulation at forty-nine C.F.R. 100–185 .
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physical gamble pictograms [edit ]
health gamble pictograms [edit ]
Pictogram Usage
- Acute toxicity (oral, dermal, inhalation), categories 1, 2, 3
- e.g. Manganese heptoxide (fire diamond rating at health hazard is 4)
GHS06: Toxic
- Acute toxicity (oral, dermal, inhalation), category 4
- Skin irritation, categories 2, 3
- Eye irritation, category 2A
- Skin sensitization, category 1
- Specific target organ toxicity following single exposure, category 3
- Respiratory tract irritation
- Narcotic effects
not use [ three ]
- with the “skull and crossbones” pictogram
- for skin or eye irritation if:
- the “corrosion” pictogram also appears
- the “health hazard” pictogram is used to indicate respiratory sensitization
GHS07: Harmful
- Respiratory sensitization, category 1
- Germ cell mutagenicity, categories 1A, 1B, 2
- Carcinogenicity, categories 1A, 1B, 2
- Reproductive toxicity, categories 1A, 1B, 2
- Specific target organ toxicity following single exposure, categories 1, 2
- Specific target organ toxicity following repeated exposure, categories 1, 2
- Aspiration hazard, categories 1, 2
- e.g. Chromium
GHS08: Health hazard
- Acute toxicity (oral, dermal, inhalation), category 5
- Eye irritation, category 2B
- Reproductive toxicity – effects on or via lactation
no pictogram required physical and health venture pictograms [edit ]
Pictogram Usage
- Explosives, divisions 1.5, 1.6
- Flammable gases, category 2
- Self-reactive substances and mixtures, type G (see HAZMAT Class 4 Flammable solids)
- Organic peroxides, type G
- Skin corrosion, categories 1A, 1B, 1C
- Serious eye damage, category 1
GHS05: Corrosive environmental hazard pictograms [edit ]
Pictogram Usage
- Acute hazards to the aquatic environment, category 1
- Chronic hazards to the aquatic environment, categories 1, 2
- Environmental toxicity, categories 1, 2
GHS09: Environmental hazard
- Acute hazards to the aquatic environment, categories 2, 3
- Chronic hazards to the aquatic environment, categories 3, 4
no pictogram required ecstasy pictograms [edit ]
class one : explosive [edit ]
Pictogram Usage
- Explosives
- Division 1.1: Substances and articles which have a mass explosion hazard
- Division 1.2: Substances and articles which have a projection hazard but not a mass explosion hazard
- Division 1.3: Substances and articles which have a fire hazard and either a minor blast hazard or a minor projection hazard or both, but not a mass explosion hazard
Note : The asterisk equal replace aside the class number and compatibility code
Divisions 1.1–1.3 Explosives – substance and article which be classify vitamin a explosive merely which salute no significant gamble Note : The asterisk be replace by the compatibility code Division 1.4 Explosives – very insensitive kernel which consume a mass explosion luck Note : The asterisk be substitute aside the compatibility code Division 1.5 Explosives – no hazard affirmation Note : The star be replace by the compatibility code Division 1.6 course two : gas [edit ]
Pictogram Usage Flammable gases – natural gas which at twenty °C and a standard press of 101.3 kPa :
- are ignitable when in a mixture of 13 percent or less by volume with air; or
- have a flammable range with air of at least 12 percentage points regardless of the lower flammable limit.
alternative sign
Division 2.1 Non-flammable non-toxic gases – boast which :
- are asphyxiant – gases which dilute or replace the oxygen normally in the atmosphere; or
- are oxidizing – gases which may, generally by providing oxygen, cause or contribute to the combustion of other material more than air does; or
- do not come under the other divisions.
alternative sign
Division 2.2 Toxic gases – accelerator which :
- are known to be so toxic or corrosive to humans as to pose a hazard to health; or
- are presumed to be toxic or corrosive to humans because they have an LC50 value equal to or less than 5000 ml/m3 (ppm).
e.g. hydrogen cyanide
Division 2.3 class three and four : flammable liquid and solid [edit ]
Pictogram Usage Flammable liquids – liquid which have ampere flash target of less than sixty °C and which equal capable of prolong combustion alternative sign
Class 3 Flammable solids, self-reactive substances and solid desensitized explosives – solid which, under condition meet in enchant, are readily combustible oregon whitethorn induce oregon contribute to fire through clash ; self-reactive substance which be liable to undergo adenine powerfully exothermic reaction ; solid desensitize explosive which may explode if not dilute sufficiently Division 4.1 Substances liable to spontaneous combustion – message which embody liable to spontaneous heat under normal conditions run into inch transportation, oregon to heat up in contact with publicize, and constitute then apt to catch fire e.g. manganese heptoxide Division 4.2 Substances which in contact with water emit flammable gases – substance which, by interaction with water, be apt to become spontaneously flammable operating room to give off flammable gasoline in dangerous quantity alternative sign Division 4.3 other GHS transportation classify [edit ]
Pictogram Usage Oxidizing substances – substance which, while indiana themselves not necessarily combustible, may, broadly aside yielding oxygen, lawsuit, oregon lend to, the combustion of other material Division 5.1 Organic peroxides – organic meaning which check the bivalent –O–O– structure and may be consider derivative of hydrogen hydrogen peroxide, where one operating room both of the hydrogen atom rich person embody substitute aside constituent radical alternative sign Division 5.2 Toxic substances – substance with associate in nursing LD50 value ≤ three hundred mg/kg ( oral ) oregon ≤ thousand mg/kg ( dermal ) operating room associate in nursing LC50 value ≤ 4000 ml/m3 ( inhalation of dust oregon mist ) e.g. about everything that contain nitrile group Division 6.1 Corrosive substances – substance which :
- cause full thickness destruction of intact skin tissue on exposure time of less than 4 hours; or
- exhibit a corrosion rate of more than 6.25 mm per year on either steel or aluminium surfaces at 55 °C
Class 8 Non-GHS tape drive pictograms [edit ]
The take after pictograms be admit in the united nations model regulation merely have not cost incorporate into the GHS because of the nature of the guess .
Class 6.2 Class 7 Class 9 Infectious substances Radioactive material Miscellaneous dangerous substances and articles note [edit ]
- ^ part one, section 1.4.10.5.1, GHS Rev.2
- ^ part one, segment 1.4.10.5.2, GHS Rev.2
- ^ separate one, section 1.4.10.5.3.1, GHS Rev.2
reference [edit ]
- “Globally Harmonized System of Classification and Labelling of Chemicals” ( pdf )
. 2021. Annex 3: Codification of Statements and Pictograms (pp 268–385).
- GHS pictogram gallery from the United Nations Economic Commission for Europe